CHEMORHEOLOGICAL ANALYSIS OF FREE RADICAL POLYMERIZATION PROCESSES DURING REACTIVE EXTRUSION
نویسندگان
چکیده
منابع مشابه
Preparation of Reactive and Thermal Stable Hyperbranched Graft Copolymers/ Clay Nanocomposite via ‘Living’ Free Radical Polymerization
Exfoliated poly (Chloromethyl styrene-co-styrene)-g-polyacrylonitryle/organo- modified montmorillonite [P(CMSt-co-St)-g-PAN/O-MMT] nanocomposite was synthesized through solution intercalation method by using atom transfer and nitroxide mediated radical polymerization. At first, poly (chloromethyl styrene-costyrene) copolymer was synthesized by nitroxide - mediated “living” free radical polyme...
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At low pressure, ethylene gas consists of single translating and rotating molecules and behaves as an ideal gas. With decrease of free volume by compression, various rotating supramolecular particles are formed, which require less space for the movement: molecular pairs, bimolecules and oligomolecules. The appearance of a new kind of particles is manifested as a phase transition of the second o...
متن کاملpreparation of reactive and thermal stable hyperbranched graft copolymers/ clay nanocomposite via ‘living’ free radical polymerization
exfoliated poly (chloromethyl styrene-co-styrene)-g-polyacrylonitryle/organo- modified montmorillonite [p(cmst-co-st)-g-pan/o-mmt] nanocomposite was synthesized through solution intercalation method by using atom transfer and nitroxide mediated radical polymerization. at first, poly (chloromethyl styrene-costyrene) copolymer was synthesized by nitroxide - mediated “living” free radical polyme...
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Frontal polymerization is a process of converting a monomer into a polymer by means of a self-propagating thermal reaction wave. We study initiation of polymerization waves by a high temperature heat source. A five species reaction model is considered with a focus on the evolution of two of these species and the temperature of the mixture. The temperature is tracked from the inert heating to th...
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Overcoming the challenge of metal contamination in traditional ATRP systems, a metal-free ATRP process, mediated by light and catalyzed by an organic-based photoredox catalyst, is reported. Polymerization of vinyl monomers are efficiently activated and deactivated with light leading to excellent control over the molecular weight, polydispersity, and chain ends of the resulting polymers. Signifi...
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ژورنال
عنوان ژورنال: Acta Polymerica Sinica
سال: 2009
ISSN: 1000-3304
DOI: 10.3724/sp.j.1105.2007.01135